An important criterion for epoxy resins is the epoxide group content. Epoxy Chemical Resistance Chart Epoxy Chemical Resistance Selection Guide. Fields marked with * are required so that we may expedite your request. In general, epoxies are known for their excellent adhesion, chemical and heat resistance, good-to-excellent mechanical properties and very good electrical insulating properties. Epoxy paints tend to deteriorate, known as "chalking out", due to UV exposure.. Bisphenol F may undergo epoxy resin formation in a similar fashion to bisphenol A. As a result, a typical formulator sells dozens or even thousands of formulationsâeach tailored to the requirements of a particular application or market. Find high quality Epoxy Chemical Formula Suppliers on Alibaba. Also aliphatic glycidyl epoxy resins usually have a low viscosity compared to aromatic epoxy resins. Use of a difunctional or polyfunctional amine forms a three-dimensional cross-linked network.  As the molecular weight of the resin increases, the epoxide content reduces and the material behaves more and more like a thermoplastic. Epoxy resins are generally combined with curing agents, modifiers and other additives into formulated coatings, adhesives, compounds or mixtures which deliver the needed performance for a specific end use or application.The formulations and systems information provided in this section can be utilized as a starting point, or baseline, for further work or development of new systems. Over the past few decades concern about the possible adverse health effects of many aromatic amines has led to increased use of aliphatic or cycloaliphatic amine alternatives. Simple epoxides are often referred to as oxides. Epoxy resins are used to bond copper foil to circuit board substrates, and are a component of the solder mask on many circuit boards. This has led to the term âmodified epoxy resinâ to denote those containing viscosity-lowering reactive diluents. As with other classes of thermoset polymer materials, blending different grades of epoxy resin, as well as use of additives, plasticizers or fillers is common to achieve the desired processing or final properties, or to reduce cost. Epoxies can be used to plug selective layers in a reservoir which are producing excessive brine. Is Epoxy-Based Polymer Suitable for Water Shut-Off Application? However, polyester resins are much cheaper. Bisphenol A-based resins are the most widely commercialised resins but also other bisphenols are analogously reacted with epichlorohydrin, for example Bisphenol F. In this two-stage reaction, epichlorohydrin is first added to bisphenol A (bis(3-chloro-2-hydroxy-propoxy)bisphenol A is formed), then a bisepoxide is formed in a condensation reaction with a stoichiometric amount of sodium hydroxide. Thus amine structure is normally selected according to the application. Typical fiber reinforcements include glass, carbon, Kevlar, and boron. Very latent hardeners enable one-component (1K) products to be produced, whereby the resin and hardener are supplied pre-mixed to the end user and only require heat to initiate curing.  Devoe & Raynolds, which was active in the early days of the epoxy resin industry, was sold to Shell Chemical; the division involved in this work was eventually sold, and via a series of other corporate transactions is now part of Hexion Inc... Bisphenol A is the chemical product of … Temperature resistance generally increases in the same order, since aromatic amines form much more rigid structures than aliphatic amines. Depending on the properties required, the ratio may be anything from 1:1 or over 10:1, but in every case they must be mixed exactly. Epoxy resins may be reacted (cross-linked) either with themselves through catalytic homopolymerisation, or with a wide range of co-reactants including polyfunctional amines, acids (and acid anhydrides), phenols, alcohols and thiols (usually called mercaptans). Starting Formulations. They are rarely used alone, but are rather employed to modify (reduce) the viscosity of other epoxy resins. When using latent hardeners, the epoxy resin and hardener may be mixed and stored for some time prior to use, which is advantageous for many industrial processes. Chemical Resistance and Secondary Containment, Primers, Sealers and Waterproofing Systems, Can, Coil and General Industrial Coatings, Protective, Marine and Shipping Container Coatings, Railway, Motorcycles and Specialized Vehicles, Cabinets, Countertops and Flooring Laminates, Epoxy Resins, Curing Agents and Modifiers, Semi-solid, Solid and Powder Grade Resins, Construction and Infrastructure Adhesives, Particleboard and Medium Density Fiberboard, Agricultural, Construction and Earthmoving (ACE) Equipment, Truck and Bus, SF 1013 White Enamel 828and1001 3140and3502, SF 1035 Heavy Tank Lining 1001and1007 3213, SF 1201 Low Whire Enamels 828 3292and3251, SF 1202 Low White Enamels 8021 3292and3378, SF 1700 WB White Primer 6520 6870 (less than 100 g/L VOC), SF 1702 Waterborne White Enamel 6520 6870, SF 1703 Waterborne Clear Coating 6520 6870, SF 1705 Waterborne White Enamel 6520 6870, SF 1728 Waterborne Gray Midcoat 6520 6870 (less than 100 g/L VOC), SF 1729 WB Red Primer 6520 6870 (less than 100 g/L VOC), SF 1741 WB White Primer - 6520 6870 (less than 100 g/L VOC), SF 1742 WB Gloss White Enamel 6520 6870 (less than 100 g/L VOC), SF 1808 Solvent Resistant Primer 5522 8290, SF 1823 Gloss White Enamel 3520 and 3546 8290, SF 1824 Gloss White Enamel 3520and3546 8290, SF 1825 Waterborne Red Primer 3520and3546 8290, SF 2000 Two-Package Clear Coating 1007 21-511, SF 2006 Black Semi-Gloss Enamel 1007F 227-8, SF 2014 Aluminum Baking Finish 1007F 21-511, SF 2017 Gray Appliance Primer 1007F 21-511, SF 2502 Phenolic Clear Bake Coating 3540-WY-55, SF 2800 Chemical Resistant Epoxy Powder Coating 1007F SU-8, SF 2802 Red Powder Coating for Pipe and Rebar Application 2024 P-104, SF 4001 Rapid Cure Adhesive 8111 3270 and 3271, SF 4005 General Purpose Epoxy Adhesive 828 3055, SF 4006 Water-Reducible Bond Coat WD-510 3072, SF 4007 High Strength Adhesive 828 3046 505, SF 4009 Adhesive Formulations EPON and Epikure, SF 4010 Equal Volume Adhesive 828 505 3125and3271, SF 4011 Heat Epoxy Adhesive 828 3234 and Aromatic Amines, SF 4013 Epoxy Marker Adhesive CS-241 3271and3153, SF 4018 High Cure Adhesive 828and58034 3072, SF 4021 Economical One-Package Adhesive 828 BF Catalyst, SF 4022 One-Package Adhesive 828 Dicyandiamide, SF 4023 One-Package Adhesive 828and58034 Latent, SF 4025 One-Package Adhesive 828 Dicyandimide, SF 4027 Room Volume Adhesive 815 3125and3055and3253, SF 4029 One-Package Temperature Adhesive 828, SF 4030 Fast-Setting Clear Adhesive 828 3270 3253, SF 4031 One-Package Adhesive 828 Dicyandiamide, SF 5001 Exposed Aggregate Matrix 828 505 and 8 3295, SF 5002 Patching Exterior Concrete 8131 3072, SF 5003 Chemical Tank Lining 813 3370and3271, SF 5006 Flexible Caulking Compound 828 3055, SF 5007 Flexible Caulking Compound 828 3055, SF 5008 Epoxy-Modified Cement Concrete WD-510 3072, SF 5009 Epoxy Modified Mortar WD-510 3046, SF 6000 Epoxy Terrazzo Flooring 828 505 and 3295, SF 6002 Industrial Floor Topping 828 and 813 3072 505, SF 6003 Electrically Conductive Topping 813 505 3072and3271, SF 6005 Chemical Resistant Topping 828 62 3370, SF 6008 Waterborne Epoxy Binder WD-510 3277, SF 6009 General Purpose Topping 828 8 3277 and 3271, SF 6010 Epoxy Glaze Coat 828 and 8021 3370, SF 6011 Epoxy Floor Coating 828and8021 3370, SF 6017 Waterborne Self-Leveling 8535-W-60 3510-W-60, SF 6018 Chemical Resistant Glaze 828 3383, SF 6019 Chemical Resistant Coating 828 3251, SF 6020 Highly Flexible Flooring 815C 3164, SF 6021 Ground Rubber Overlayment 8132 3164, SF 7000 Flexibilized Impregnating Compound 828 32, SF 7001 Flame Retardant Compound 828and1163 56, SF 7002 Glass-Filled Epoxy 828 505Starting Formulation 7002, SF 7003 Rapid Curing Potting Compound 828 62 3271, SF 7005 Epoxy Casting Compound 828 505 3046 and 3234, SF 7006 Epoxy Casting Compound 828 505 3234, SF 7007 Rapid Curing Compound 813 and 828 3271, SF 7011 General Purpose Compounding 1002F, SF 7018 General Purpose Potting Compound 828, SF 7019 Thermal Shock Resistant Compound 828 505, SF 8000 Pre-Preg Laminating Compound SU-8, SF 8002 Flame Laminating Compound SU-8and1163, SF 8009 Wet Laminating Binder 828 and 8132 3295, SF 8017: Epoxy Resin System 826 862 LS-81K, SF 8038: FlameX™ Epoxy Resin System for Infusion and RTM of Aerospace Interior Parts, SF 8039: Toughened Epoxy Resin Systems for Filament Winding, SF 9000: Epoxy Dispersion Formulations Cured with Dicyandiamide, SF 9002: Preparing Waterborne Dispersions of Elastomer Modified Epoxy Resins. For the chemical group, see. 30 000 â 70 000 g/mol) form a class known as phenoxy resins and contain virtually no epoxide groups (since the terminal epoxy groups are insignificant compared to the total size of the molecule). increasingly, WATER BASED polyamines are also used to help reduce the toxicity profile among other reasons. It represents the smallest type of epoxy resin. In principle, any molecule containing a reactive hydrogen may react with the epoxide groups of the epoxy resin. Epoxy resin is superior to other types of resins because it has low shrink during cure, and excellent moisture and chemical resistance. Epoxy materials tend to harden somewhat more gradually, while polyester materials tend to harden quickly, particularly if a lot of catalyst is used. Do-it-yourself epoxy paints (different from true floor coatings) are often water or solvent-based and rely mainly, if not exclusively, on evaporation to harden and dry the final product. However, the commercial use of fluorinated epoxy resins is limited by their high cost and low Tg. We appreciate the opportunity to hear your.  Curing of epoxy resins is an exothermic reaction and in some cases produces sufficient heat to cause thermal degradation if not controlled. BASF’s intermediates make essential contributions to our daily lifes. The chemistry of epoxies and the range of commercially available variations allows cure polymers to be produced with a very broad range of properties. Epoxy resin, mixed with pigment, may be used as a painting medium, by pouring layers on top of each other to form a complete picture. Allergic reaction is often visible in the form of dermatitis, particularly in areas where the exposure has been highest (commonly hands and forearms). From coatings to transportation and energy to construction, we’ve been enabling progress through Responsible Chemistry for over half a century. 1-Butene oxide will volatilize from water and soil. Solid epoxy resins are generally safer than liquid epoxy resins, and many are classified non-hazardous materials. How Formula Impacts Performance. by secondary hydroxyl groups in the epoxy resin. Epoxy coatings are also widely used as primers to improve the adhesion of automotive and marine paints especially on metal surfaces where corrosion (rusting) resistance is important. Coatings Calculator. By contrast, polyester resins can only bond using the first two of these, which greatly reduces their utility as adhesives and in marine repair. In some cases, blends of dianhydrides and monoanhydrides can improve metering and mixing with liquid epoxy resins. 2 Experimental Section. Aromatic amines were widely used as epoxy resin hardeners, due to the excellent end properties when mixed with a parent resin. They can be used as adhesives for wood, metal, glass, stone, and some plastics. In general, uncured epoxy resins have only poor mechanical, chemical and heat resistance properties. . The epoxy resin market is dominated by the Asia-Pacific region, which contributes 55.2% of the total market share. The same applies to transformers, bushings, spacers, and composites cables connecting the windmills to the grid In Europe, wind energy components account for the largest segment of epoxy applications, about 27% of the market.. In 1946, Sylvan Greenlee, working for the Devoe & Raynolds Company, patented resin derived from bisphenol-A and epichlorohydrin. The variety of combinations of epoxy resins and reinforcements provides a wide latitude in properties obtainable in molded parts. These resins typically display low viscosity at room temperature (10-200 mPa.s) and are often referred to as reactive diluents. Insufficient heat during cure will result in a network with incomplete polymerisation, and thus reduced mechanical, chemical and heat resistance. Slower reactivity allows longer working times for processors. The amount and type of hardener needed depends on the type of epoxy resin being used. Epoxies are also used in producing fiber-reinforced or composite parts.
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